Lithium niobate (LN) is a multifunctional crystal important, has excellent piezoelectric properties,
nonlinear optical properties, electro-optic and photorefractive properties etc.. The growth of large size crystal using the Czochralski method, and easy processing. Therefore, lithium niobate crystal is a kind of widely used and important functional materials. LN crystal is a kind of typical non-stoichiometric crystal. General condition is grown by the Czochralski method in the congruent LiNbO3 crystal (CLN) is in congruent ratio ([Li]/[Nb]=48.6/51.4) of the growth melt, deletion of Li ions are caused by the large number of vacancy defects in the crystal, so that many physical properties of LN crystal has been greatly influence.
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